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Oxy-fuel Combustion for Power Generation and Carbon Dioxide (CO2) Capture

Woodhead Publishing Ltd, February 2011, Pages: 400

Oxy-fuel combustion is currently considered to be one of the major technologies for carbon dioxide (CO2) capture in power plants. The advantages of using oxygen (O2) instead of air for combustion include a CO2-enriched flue gas that is ready for sequestration following purification and low NOx emissions. This simple and elegant technology has attracted considerable attention since the late 1990s, rapidly developing from pilot-scale testing to industrial demonstration. Challenges remain, as O2 supply and CO2 capture create significant energy penalties that must be reduced through overall system optimisation and the development of new processes.

"Oxy-fuel combustion for power generation and carbon dioxide (CO2) capture" comprehensively reviews the fundamental principles and development of oxy-fuel combustion in fossil-fuel fired utility boilers. Following a foreword by Professor János M. Beér, the book opens with an overview of oxy-fuel combustion technology and its role in a carbon-constrained environment. Part one introduces oxy-fuel combustion further, with a chapter comparing the economics of oxy-fuel vs. post-/pre-combustion CO2 capture, followed by chapters on plant operation, industrial scale demonstrations, and circulating fluidized bed combustion. Part two critically reviews oxy-fuel combustion fundamentals, such as ignition and flame stability, burner design, emissions and heat transfer characteristics, concluding with chapters on O2 production and CO2 compression and purification technologies. Finally, part three explores advanced concepts and developments, such as near-zero flue gas recycle and high-pressure systems, as well as chemical looping combustion and utilisation of gaseous fuel.

With its distinguished editor and internationally renowned contributors, "Oxy-fuel combustion for power generation and carbon dioxide (CO2) capture" provides a rich resource for power plant designers, operators, and engineers, as well as academics and researchers in the field.

Key features:

- comprehensively reviews the fundamental principles and development of oxy-fuel combustion in fossil-fuel fired utility boilers
- provides an overview of oxy-fuel combustion technology and its role in a carbon-constrained environment
- introduces oxy-fuel combustion comparing the economics of oxy-fuel vs. post-/pre-combustion CO2 capture
- critically reviews oxy-fuel combustion fundamentals, such as ignition and flame stability, burner design, emissions and heat transfer characteristics

Overview of oxy-fuel combustion technology for carbon dioxide (CO2) capture
L Zheng, CanmetENERGY, Canada
- Introduction
- Oxy-fuel combustion: concepts and components
- Oxy-fuel combustion: background and motivation
- Existing challenges for oxy-fuel combustion technology
- Development of oxy-fuel combustion technology
- About this book
- Acknowledgements
- References

PART 1: INTRODUCTION TO OXY-FUEL COMBUSTION

Economic comparison of oxy-coal carbon dioxide (CO2) capture and storage (CCS) with pre- and post-combustion CCS
D Thimsen, J Wheeldon and D Dillon, Electric Power Research Institute (EPRI), USA
- Introduction
- Oxy-coal power plant systems scope
- Oxy-coal carbon dioxide (CO2) capture and storage (CCS) cost estimates and comparisons with post- and pre-combustion CO2 capture
- Conclusions

Oxy-fuel power plant operation
Y Tan, CanmetENERGY, Canada
- Introduction
- Flue gas recycle system
- Oxygen (O2) handling
- Leakages
- Slagging and ash formation
- Flue gas cleaning equipment
- Maintenance of oxy-fuel power plants
- Plant control systems
- Conclusion
- References

Industrial scale oxy-fuel technology demonstration
T Wall and R Stanger, The University of Newcastle, Australia
- Introduction
- Oxy-fuel demonstrations and large pilot-plants
- Demonstrations and progress towards commercial deployment
- Conclusions
- Pre-printing update
- Acknowledgements
- References

Oxy-fuel combustion on circulating fluidized bed (CFB)
E J Anthony, CanmetENERGY, Canada and H Hack, Foster Wheeler North America Corporation, USA
- Introduction
- Early work
- Other test facilities
- CanmetENERGY tests
- Longer duration sulphation tests
- Large pilot-scale and demonstration projects
- References

PART 2: OXY-FUEL COMBUSTION FUNDAMENTALS

Ignition, flame stability, and char combustion in oxy-fuel combustion
C Shaddix, Sandia National Laboratories, USA and A Molina, National University of Colombia, Colombia
- Introduction
- Coal ignition
- Flame stability
- Char combustion
- Carbon burnout
- Conclusions and future trends
- References

Oxy-coal burner design for utility boilers
J Shan, Siemens Energy and A Fry, Reaction Engineering International, USA
- Introduction
- Overview of air-fired burner design methodology
- Changes to burner design criteria and constraints
- Oxy-coal burner principles
- Commercial oxy-coal burners
- Conclusions
- References

Pollutant formation and emissions from oxy-coal power plants
Y Tan, CanmetENERGY, Canada
- Introduction
- Nitrogen oxide (NOx) emissions
- Sulphur oxide (SOx) emissions
- Mercury and trace elements
- Ash formation
- Integrated emissions control
- Vent stream from flue gas compression train
- Conclusion
- References

Oxy-fuel heat transfer characteristics and impacts on boiler design
Y Liu, T Wall, S Khare The University of Newcastle, Australia and R Gupta, The University of Alberta, Canada
- Introduction
- Heat transfer criteria for oxy-fuel combustion
- Theoretical heat transfer analysis
- Computational fluid dynamics (CFD) radiation heat transfer models
- Conclusions
- Acknowledgements
- References

Current and future oxygen (O2) supply technologies for oxy-fuel combustion
N M Prosser and M M Shah, Praxair, Inc., USA
- Introduction
- Oxygen supply needs for oxy-coal power plants
- Vacuum pressure swing adsorption technology
- Cryogenic air separation technology
- Oxygen transport membrane (OTM) technology
- Future trends
- Acknowledgements
- References

Carbon dioxide (CO2) compression and purification technology for oxy-fuel combustion
M M Shah, Praxair, Inc., USA
- Introduction
- Industrial carbon dioxide (CO2) production process
- Oxy-fuel flue gas CO2 purification process
- Recent advances in the oxy-fuel flue gas CO2 purification technology
- Environmental performance of oxy-fuel power plant
- Future trends
- Conclusion
- Acknowledgements
- References

PART 3: ADVANCED OXY-FUEL COMBUSTION CONCEPTS AND DEVELOPMENTS

Direct oxy-coal combustion with minimum or no flue gas recycle
S Kobayashi and L E Bool, Praxair, Inc., USA
- Introduction
- Prior work on near zero flue gas recycle oxy-fuel fired boilers
- Design considerations for near zero flue gas recycle
- Separate fired chambers for different steam circuits
- Furnace with controlled radiant heating of superheaters and reheaters
- Furnace with distributed firing
- Furnace with multiple partition walls
- Conclusion
- References

High pressure oxy-fuel (HiPrOx) combustion systems
B Clements, R Pomalis, L Zheng and T Herage, CanmetENERGY, Canada
- Introduction
- Rankine cycle power systems
- Uses of pressure in power systems
- Equipment and operational considerations
- Other high pressure power generation systems
- The industrial sector
- Future trends
- Acknowledgements
- References

Chemical-looping combustion for power generation and carbon dioxide (CO2) capture
H Jin and X Zhang, Chinese Academy of Sciences, P. R. China Introduction
- Principle of systems integration for chemical-looping combustion (CLC)
- Solid looping materials
- Design of chemical-looping combustion systems
- Chemical-looping combustion systems with different fuels
- Future trends
- Conclusions
- References

Oxy-fuel combustion of gaseous fuel
N Zhang and W Han, Chinese Academy of Sciences, P. R. China
- Introduction
- Thermodynamic cycles with conventional air separation technology
- Thermodynamic cycles with advanced air separation technologies
- Use of solid fuel with gasification technology
- Future trends
- References

Dr Ligang Zheng is a Research Scientist at CanmetENERGY, Natural Resources Canada. He is noted for his research in energy system technical feasibility studies and optimisation, and has also chaired the oxy-fuel combustion panel and technical sessions at the Clearwater Clean Coal Conference since 2005.

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