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Chemistry and Technology of Carbodiimides

John Wiley and Sons Ltd, Sep 2007, Pages: 312


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Carbodiimides are molecules containing the functional group N=C=N. They play an important role as condensation agents in the synthesis of polypeptides, polynucleotides, polysaccharides and numerous other chemical transformations. Carbodiimides also act as zero-length crosslinkers for proteins. In industry, applications include the stabilization of the major global diisocyanate MDI, polyester based polymers and herbicides. Metal substituted carbodiimides are used as precursors for ceramic materials, while sulfonylcarbodiimides are used as precursors for antidiabetic drugs and herbicides.  

Chemistry and Technology of Carbodiimides highlights the synthesis, reactions and industrial importance of this important class of chemicals, including:  

-Alkyl and Arylcarbodiimides
-Unsaturated Carbodiimides
-Halogenated Carbodiimides
-Functional Carbodiimides
-Silyl Carbodiimides
-Phosphorus Substituted Carbodiimides
-Sulfonyl Carbodiimides
-Amino Substituted Carbodiimides
-Metal Substituted Carbodiimides
-Cyclic Carbodiimides
-Polymeric Carbodiimides
-Applications in Organic Synthesis
-Biological Applications, including antibiotic synthesis, protein and DNA synthesis, modifications of proteins, crosslinking of proteins, and pharmaceutical applications
-Polymer and Industrial Applications, including polymer modification, carbodiimides as stabilizers, carbodiimides in dye applications, and other applications

Authors Bio:

Dr Henri Ulrich. Dr Ulrich is well known as an outstanding expert in heterocumulene chemistry in general, in particular dealing with isocyanates and carbodiimides. He is also well known for his important contributions to polymer chemistry, in particular from an industrial point of view. Coming from industry his work is focused on synthetic chemistry and practical applications rather than theoretical considerations.


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