Anion Coordination Chemistry

  • ID: 2078467
  • Book
  • 574 Pages
  • John Wiley and Sons Ltd
1 of 4
Building on the pioneering work in supramolecular chemistry from the last 20 years or so, this monograph addresses new and recent

approaches to anion coordination chemistry. Synthesis of receptors, biological receptors and metallareceptors, the energetics of anion binding, molecular structures of anion complexes, sensing devices are presented and computational studies addressed to aid with the understanding of the different driving forces responsible for anion complexation. The reader is promised an actual picture of the state of the art for this exciting and constantly evolving field of supramolecular anion coordination chemistry. The topics range from ion channels to selective

sensors, making it attractive to all researchers and PhD students with an interest in supramolecular chemistry.
Note: Product cover images may vary from those shown
2 of 4
Preface

ASPECTS OF ANION COORDINATION FROM HISTORICAL PERSPECTIVES

Introduction

Halide and Pseudohalide Anions

Oxoanions

Phosphate and Polyphosphate Anions

Carboxylate Anions and Amino Acids

Anionic Complexes: Supercomplex Formation

Nucleotides

Final Notes

THERMODYNAMIC ASPECTS OF ANION COORDINATION

Introduction

Parameters Determining the Stability of Anion Complexes

Molecular Recognition and Selectivity

Enthalpic and Entropic Contributions in Anion Coordination

STRUCTURAL ASPECTS OF ANION COORDINATION CHEMISTRY

Introduction

Basic Concepts of Anion Coordination Chemistry

Classes of Anion Hosts

Acycles

Monocycles

Cryptands

Transition–Metal–Assisted Ligands

Lewis Acid Ligands

Conclusion

SYNTHETIC STRATEGIES

Introduction

Design and Synthesis of Polyamine–Based Receptors for Anions

Design and Synthesis of Amide Receptors

TEMPLATE SYNTHESIS

Introductory Remarks

Macrocyclic Systems

Bowl–Shaped Systems

Capsule, Cage, and Tube–Shaped Systems

Circular Helicates and meso–Helicates

Mechanically Linked Systems

Concluding Remarks

ANION–PI INTERACTIONS IN MOLECULAR RECOGNITION

Introduction

Physical Nature of the Interaction

Energetic and Geometric Features of the Interaction Depending on the Host (Aromatic Moieties) and the Guest (Anions)

Influence of Other Noncovalent Interactions on the Anion–Pi Interaction

Experimental Examples of Anion–Pi Interactions in the Solid State and in Solution

Concluding Remarks

RECEPTORS FOR BIOLOGICALLY RELEVANT ANIONS

Introduction

Phosphate Receptors

Carboxylate Receptors

Conclusion

SYNTHETIC AMPHIPHILIC PEPTIDES THAT SELF–ASSEMBLE TO MEMBRANE–ACTIVE ANION TRANSPORTS

Introduction and Background

Biomedical Importance of Chloride Channels

The Development of Synthetic Chloride Channels

Approaches to Synthetic Chloride Channels

The Development of Amphiphilic Peptides as Anion Channels

Structural Variations in the SAT Modular Elements

Conclusions

ANION SENSING BY FLUORESCENCE QUENCHING OR REVIVAL

Introduction

Anion Recognition by Dynamic and Static Quenching of Fluorescence

Fluorescent Sensors Based on Anthracene and on a Polyamine Framework

Turning on Fluorescence with the Indicator Displacement Approach
Note: Product cover images may vary from those shown
3 of 4

Loading
LOADING...

4 of 4
Kristin Bowman–James
Antonio Bianchi
Enrique García–Espana
Note: Product cover images may vary from those shown
5 of 4
Note: Product cover images may vary from those shown
Adroll
adroll