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Reagents for Direct Functionalization of C-H Bonds. Edition No. 1. Handbook of Reagents for Organic Synthesis

  • ID: 2169257
  • Book
  • October 2006
  • 424 Pages
  • John Wiley and Sons Ltd
A concise and informative collection of articles on the synthesis of organic, biological and medicinal materials.
Key Features:
  • Detailed information on 200 reagents to be used for the functionalization of C-H bonds in the carbon backbone of organic molecules
  • A systematic approach to the use of organometallic compounds in organic synthesis
  • Articles will stress chemical aspects such as yield, conversion, specifity [enantio, stereo, regio, chemo], and where applicable, catalyst loading/turnover
Note: Product cover images may vary from those shown
Preface ix

Introduction 1

Recent Review Articles and Monographs 9

Allyl Triflone 11

2-Amino-3-Picoline 12

1,2-Benziodoxoyl-3(1H)-one Derivatives 17

2,2-Bis{lcub}[2-[4(S)-tert-butyl-1,3-oxazinyl]{rcub} propane 20

Bis(cyclopentadienyl)methylzirconium Tetraphenylborate-Tetrahydrofuran 26

Bis[dimethyl([micro]-dimethyl sulfide)-platinum(II)] 28

N-Bromosuccinimide 30

Carbon Tetrabromide 41

Carbon Tetraiodide 43

4-(4-Chlorophenyl)-3-hydroxy-2(3H) thiazolethione 45

Chromium(VI) Oxide 48

Chromium(VI) Oxide-3,5-Dimethylpyrazole 53

Chromium(VI) Oxide-Dipyridine 54

Chromyl Acetate 57

Copper(I){lcub}Hydrotris(3,4,5-tribromo)pyrazolylborate{rcub}(acetonitrile) 60

Copper(I),[Hydrotris[3-(2,4,6-trimethylphenyl)-1H-pyrazolato-N[subscript 1]] borato(1-)-N[subscript 2],N[prime][subscript 2]N[tprime][subscript 2] 63

Copper(II) Acetate 64

Copper(II) Chloride 71

Di-(-)-(1R,2S)-2-phenyl-l-cyclohexyl Diazenedicarboxylate 79

(Diacetoxyiodo)benzene 80

Dibenzoyl Peroxide 89

Di-t-butyl Chromate 99

Di-t-butyl Peroxide 102

Dimethyl Diazomalonate 107

Dimethyldioxirane 113

Dipotassium Tetrachloroplatinate(II) 119

Dirhodium(II) bis-{lcub}1,3-[N,N[prime]-di(4-Dodecyl-Benzenesulfonyl)-(2S,2[prime] S),(5R,5[prime] R)-5,5[prime]-Prolinate]Benzene{rcub} 120

Dirhodium(II) Tetra(caprolactamate) 122

Dirhodium(II) Tetrakis(perfluorobutyrate) 124

Dirhodium(II) Tetrakis(trifluoroacetate) 126

Dirhodium(II) Tetrakis(triphenylacetate) 129

Dirhodium(II) Tetraacetamide 132

Dirhodium(II) Tetraacetate 134

Dirhodium(II) Tetrakis[Alkyl 2-oxaazetidine-4(S)-carboxylate] 144

Dirhodium(II) Tetrakis[1-[[(4-dodecylphenyl]sulfonyl]-prolinate] 146

Dirhodium(II) Tetrakis[methyl 1-(3-phenylpropanoyl)-2-oxaimidazolinidinecarboxylate] 154

Dirhodium(II) Tetrakis [methyl 2-oxapyrrolidine-carboxylate] 157

Dirhodium(II) Tetrakis [methyl 2-oxooxazolidine-4(S)-carboxylate] 160

Dirhodium(II) Tetrakis[N-phthaloyl-(S)-tert-leucinate] 162

Dirhodium(II) Tetraoctanoate 166

Disodium Tetrachloroplatinate(II) 169

Ethyl Azidoformate 171

Gallium Trichloride 181

1-Hydroxy-1,2-benziodoxol-3(1H)-one 187

Hypofluorous Acid 190

Hypofluorous Acid, Acetonitrile Complex 191

Iridium(V) Pentahydrobis(isopropylphosphine) 197

Iron(II) Bis(pyridine)bis(2-pyridinecarboxylato-N1,O[subscript 2]) 198

Iron(II) Perchlorate 202

Iron(II) Phthalocyanine 202

Iron(II) 1,3,2-Benzodioxaborol-2-yldicarbonyl ([eta][superscript 5]-2,4-cyclopentadien-1-yl) 204

Mercury(0) 207

Methyl Phenyldiazoacetate 209

Methyl(trifluoromethyl)dioxirane 214

Oxaziridine, 3-Fluoro-3-(heptafluoropropyl)-2-(nonafluorobutyl) 221

Palladium(II) Acetate 229

Pinacol Diborane 253

Pinacolborane 260

Platinum(II) Chloride 263

Rhenium(VII) Methyltrioxo 271

Rhenium(VII) Aquamethyloxodiperoxy 276

Rhenium(VII) Methyloxodiperoxy 283

Rhodium(I) bis Cyclooctene Chloride Dimer 287

Rhodium(I) Carbonyl(chloro)bis(triphenylphosphine) 293

Rhodium(I) Chlorotris(triphenylphosphine) 303

Ruthenium (0) Dodecacarbonyl, Triangulo 315

Ruthenium(II) Dichlorotris(triphenylphosphine) 318

Ruthenium(II), bis[N,N-bis-[(2-pyridyl-[kappa]N)methyl]-2-pyridinemethanamine-N1,N2] di-[micro]-chloride 322

Ruthenium(III) Chloride 324

Ruthenium(III) N,N[prime],N[Prime],-Trimethyl-1,4,7-triazacyclononane + Ruthenium(II) cis-diaquabis(6,6[prime]-dichloro-2,2[prime]-bipyridine)bistriflate 328

Ruthenium(VIII) Oxide 331

Selenium(IV) Oxide 341

Silver(I) [tris[3,5-bis(trifluoromethyl)-1H-pyrazolato-N1]hydroborato(1-)-N2, N2[prime], N2[tprime]-tetrahydrofuran 343

Triethylborane 347

Trifluoromethyl Sulfonyl Ethynyl Benzene 362

Triisopropylsilylethynyl Triflone 363

Tungsten(II) Tricarbonyl(4,6-dimethyl-1,3,2-benzodioxaborol-2-yl)[(1,2,3,4,5,-[eta])-1,2,3.4,5-pentamethyl-2,4-cyclopentadien-l-yl) 364

Tungstoboric Acid, Tetrakis(tetrabutylammonium) Salt 366

Vanadium(VI) Dioxobis(pyrazine-2-carboxylate) Tetrabutylammonium 371

Vanadium(V) Diaquaoxoperoxy (2-pyridinecarboxylate-[kappa]N1, [kappa]02) 375

List of Contributors 379

Reagent Formula Index 387

Subject Index 391

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Philip L. Fuchs Purdue University, USA.
Note: Product cover images may vary from those shown
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