The Claisen Rearrangement. Methods and Applications

  • ID: 2179562
  • Book
  • 591 Pages
  • John Wiley and Sons Ltd
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The first comprehensive coverage of all facets of the Claisen rearrangement and its variants, presenting catalytic, enzymatic and theoretic aspects. As such, this book helps synthetic chemists to exploit the vast potential of this elegant C–C linking reaction, discusses a wealth of catalytic options, and gives those more theory–minded chemists a detailed insight into the mechanistic aspects of the Claisen rearrangement. The result is an invaluable source of information and a ready reference helping every organic chemist to find the best solution for their particular Claisen rearrangement problem.

From the Contents:

Chorismate Mutase–Catalyzed Claisen Rearrangement

Chiral Metal Complex–Catalyzed Aliphatic Claisen Rearrangement

Alphabetic and Aromatic Claisen Rearrangement

Metal–Catalyzed Claisen Rearrangement

Simple Enolate and Chelate Enolate Claisen Rearrangement

Claisen–Johnson Orthoester Rearrangement

The Meerwein–Eschenmoser Claisen Rearrangement

The Carroll Rearrangement

Thio–Claisen Rearrangement

Aza–Claisen Rearrangement

A must–have for all organic and catalytic chemists, as well as those working with/on organometallics, and in industry.
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Preface

Theoretical Aspects of the Claisen Rearrangement

Chorismate Mutase–Catalyzed Claisen Rearrangement

Chiral Metal Complex–Catalyzed Aliphatic Claisen Rearrangement

Alphabetic and Aromatic Claisen Rearrangement

Metal–Catalyzed Claisen Rearrangement

Simple Enolate and Chelate Enolate Claisen Rearrangement

Claisen–Johnson Orthoester Rearrangement

The Meerwein–Eschenmoser Claisen Rearrangement

The Carroll Rearrangement

Thio–Claisen Rearrangement

Aza–Claisen Rearrangement
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Martin Hiersemann
Udo Nubbemeyer
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