Boronic Acids. Preparation and Applications in Organic Synthesis, Medicine and Materials 2 Volume Set. 2nd, Completely Revised Edition

  • ID: 2179995
  • Book
  • 726 Pages
  • John Wiley and Sons Ltd
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The past two decades have witnessed phenomenal advances in the synthetic, biological, and medicinal applications of organoboronic acid derivatives. In particular, a large number of novel synthetic processes have signifi cantly expanded the breadth of usefulness of boronic acids as a class of substrates. As a result, most chemists in academia and industry now make use of boronic acids in synthetic chemistry, be it for Suzuki–Miyaura cross–coupling or other reactions. This in turn has created a new market for suppliers of functionalized boronic acids.

Following the huge success of the fi rst edition of Boronic Acids, which has become THE reference source for everyone working in the field, this completely updated edition is expanded by almost 50%. The renowned boron chemist Prof. Dennis Hall is joined by a select group of expert authors to cover all modern aspects of boronic acid derivatives in one comprehensive handbook.

From the reviews of the first edition:

"... this excellent book deserves to be on the bookshelf of all synthetic chemists, whether in discovery or process chemistry."

Organic Process Research & Development Journal

"Hall states at the outset that his task was to provide the fi rst comprehensive book on the chemistry and biology of boronic acids; this he has

done, but at the pace of current developments, a second edition might not be so long in arriving."

Angewandte Chemie IE

From the contents:

Volume 1

∗ Introduction: Structure, Properties, and Preparation of Boronic Acid Derivatives – Overview of Their Reactions and Applications (Hall)

∗ Metal–Catalyzed Borylation of C–X and C–H Bonds for the Synthesis of Boronic Esters (Miyaura and Ishiyama)

∗ Transition Metal–Catalyzed Sila– and Diborylation of Alkenes, Allenes, Dienes, and Alkynes (Suginome and Ohmura)

∗ The Contemporary Suzuki–Miyaura Reaction (Organ and Valente) Rhodium and Palladium–Catalyzed Asymmetric Conjugate Additions of Organoboronic Acids (Hayashi and Berthon–Gelloz)

∗ Recent Advances in the Chan–Lam Coupling Reaction: Copper–Promoted C–Heteroatom Bond Cross–Coupling Reactions with Boronic

Acids and Derivatives (Lam and Qiao)

Volume 2

∗ Transition Metal–Catalyzed Desulfi tative Coupling of Thioorganic Compounds with Boronic Acids (Liebeskind and Garnier–Amblard)

∗ Catalytic Additions of Allylic Boronates to Carbonyl and Imine Derivatives (Hall and Elford)

∗ Recent Advances in Nucleophilic Addition Reactions of Organoboronic Acids and their Derivatives to Unsaturated C–N Functionalities

(Batey and Ramadhar)

∗ Asymmetric Homologation of Boronic Esters with Lithiated Carbamates, Epoxides and Aziridines(Aggarwal and Webster)

∗ Organotrifluoroborates: Organoboron Reagents for the 21st Century (Molander and Jean–Gérard)

∗ Boronic Acids Derivatives as Catalysts (Yamamoto and Payette) Applications of Boronic Acids in Chemical Biology and Medicinal Chemistry

(Wang and Ni)

∗ Boronic Acids in Materials Chemistry (Lavigne and Liu)
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Introduction: Properties, Preparation, Overview of Application

Metal–Catalyzed Borylation of C–X and C–H Bonds for the Synthesis of Boronic Esters

Transition–Metal Catalyzed Sila– and Diborylation of Alkenes, Allenes, and Alkynes

The Contemporary Suzuki–Miyaura Reaction

Rhodium and Palladium–Catalyzed Asymmetric Conjugate Additions of Organoboronic Acids

Recent Advances in Chan–Lam Coupling Reaction: Copper–Promoted C–Heteroatom Bond Cross–Coupling Reactions with Boronic Acids and Derivatives

Transition–Metal Catalyzed Desulfitative Coupling of Thioorganic Compounds with Boronic Acids

Catalytic Additions of Allylic Boronates to Carbonyl and Imine Derivatives

Recent Advances in Nucleophilic Addition Reactions of Organoboronic Acids and their Derivatives to Unsaturated C?N Functionalities

Asymmetric Homologation of Boronic Esters with Lithiated Carbamates

Organotrifluoroborates: Organoboron Reagents for the 21st Century

Boronic Acids as Catalysts

Applications of boronic acids in chemical biology and medicinal chemistry

Boronic Acids in Materials Chemistry

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"Overall, Hall′s book provides an excellent starting point from which to explore the chemistry of boronic acids, but also one which gives a perspective on likely future developments. A clear positive feedback loop emerges from the material herein, whereby the take–up of new reactions and applications leads to demands for improved methods for the preparation of boronate substrates which in turn offers wider scope for further new reactivity patterns to be exploited. Hall states at the outset that his task was to provide the first comprehensive book on the chemistry and biology of boronic acids; this he has done, but at the pace of current developments, a second edition might not be so long in arriving."

Angewandte Chemie IE

"For some reason, this excellent book didn′t get reviewed as soon as it was published but we would like to remedy this now...In conclusion, this excellent book deserves to be on the bookshelf of all synthetic chemists, whether in discovery or process chemistry."

Organic Process Research & Development Journal
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