Terpyridine-based Materials. For Catalytic, Optoelectronic and Life Science Applications

  • ID: 2180128
  • Book
  • 542 Pages
  • John Wiley and Sons Ltd
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In recent years, the utilization of terpyridines both in macromolecular structure assembly and device chemistry has exploded, enabling, for

example, supramolecular polymer architectures with switchable chemical and physical properties as well as novel functional materials

for optoelectronic applications such as light–emitting diodes and solar cells. Further applications include the usage of terpyridines and their

metal complexes as catalysts for asymmetric organic reactions and, in a biological context, as anti–tumor agents or biolabels. This book covers terpyridine–based materials topics ranging from syntheses, chemistry, and multinuclear metal complexes, right up to functionalized polymers, 3D–architectures, and surfaces. Aimed at materials scientists, (in)organic chemists, polymer chemists, complex chemists, physical chemists, biochemists, and libraries.
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Preface

INTRODUCTION

SYNTHESES, PROPERTIES, AND APPLICATIONS OF FUNCTIONALIZED 2,2′:6′,2′′–TERPYRIDINES

Introduction

Basic Synthetic Strategies

Synthesis and Properties of 2,2′:6′,2′′–Terpyridine Derivatives

2,2′:6′,2′′–Terpyridines Symmetrically Substituted on the Outer Pyridine Rings

Ziessel–Type 2,2′:6′,2′′–Terpyridines

Kröhnke–Type 2,2′:6′,2′′–Terpyridines

Miscellaneous Terpyridine–Analogous Compounds

CHEMISTRY AND PROPERTIES OF TERPYRIDINE TRANSITION METAL ION COMPLEXES

Introduction

Basic Synthetic Strategies and Characterization Tools

Ru11 and Os11 Complexes

Iridium(III) Complexes with Terpyridine Ligands

Platinum(III) Mono(terpyridine) Complexes

METALLO–SUPRAMOLECULAR ARCHITECTURES BASED ON TERPYRIDINE COMPLEXES

Introduction

Terpyridine–Containing Metallo–Macrocycles

The HETTAP Concept

Racks and Grids

Helicates

Rotaxanes and Catenanes

Miscellaneous Structures

PI–CONJUGATED POLYMERS INCORPORATING TERPYRIDINE METAL COMPLEXES

Introduction

Metallo–Supramolecular Polymerization

Metallopolymers Based on Pi–Conjugated Bis(terpyridine)s

Main–Chain Metallopolymers Based on Terpyridine–Functionalized Pi–Conjugated Polymers

FUNCTIONAL POLYMERS INCORPORATING TERPYRIDINE–METAL COMPLEXES

Introduction

Polymers with Terpyridine Units in the Side Chain

Polymers with Terpyridines within the Polymer Backbone

TERPYRIDINE METAL COMPLEXES AND THEIR BIOMEDICAL RELEVANCE

Introduction

Terpyridine Metal Complexes with Biological Activity

TERPYRIDINES AND NANOSTRUCTURES

Introduction

Terpyridines and Surface Chemistry

Terpyridines and Inorganic Nanomaterials

Terpyridines and Nano–Structured TiO2: Photovoltaic Applications

Organopolymeric Resins, Beads, and Nanoparticles

CATALYTIC APPLICATIONS OF TERPYRIDINES AND THEIR TRANSITION METAL COMPLEXES

Introduction

(Asymmetric) Catalysts in Organic Reactions

Electrocatalytic Oxidation and Reduction Processes

Photocatalytic Processes

CONCLUDING REMARKS

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Ulrich S. Schubert
Andreas Winter
George R. Newkome
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