The gold standard of any scientific experiment or procedure is repeatability. Any peer should be able to produce similar results by working from the laboratory notes of the original investigator. The practice of environmental chemistry demands an even higher standard, that of "legal defensibility." Since any laboratory monitoring, no matter how routine, can easily end up as evidence in a pollution case, lab notebooks must not only show proper, repeatable scientific procedures, but also must do so in a standardized format subject to legal scrutiny.
Environmental Laboratory Exercises for Instrumental Analysis and Environmental Chemistry is a stand–alone, complete summary of laboratory work for environmental chemistry students. It presents a richly detailed set of classroom–tested experiments along with background information, safety and hazard notes, a list of chemicals and solutions needed, data collection sheets where necessary, and blank pages so students can compile results and summarize findings.
This useful resource also:
- Focuses on environmental, i.e., "dirty" samples
- Stresses critical concepts like analysis techniques and documentation
- Includes water, air, and sediment experiments
- Includes an interactive software package for pollutant fate and transport modeling exercises
- Functions as a student portfolio of documentation abilities for job or graduate school applications
- Offers instructors actual samples of student work for troubleshooting, notes on each procedure, and procedures for solutions preparation
In addition to its comprehensive presentation of laboratory and documentation exercises, this text emphasizes the essential skill of statistical analysis. A widely applicable spreadsheet exercise greatly increases student understanding of data analysis techniques and correct instrument calibration.
Environmental Laboratory Exercises for Instrumental Analysis and Environmental Chemistry provides the best and most exhaustive laboratory manual for advanced undergraduates or graduates studying instrumental analysis, environmental chemistry, or advanced analytical techniques.
TO THE INSTRUCTOR.
PART 1: PRELIMINARY EXERCISES.
1. How to Keep a Legally Defensible Laboratory Notebook.
2. Statistical Analysis.
3. Field Sampling Equipment for Environmental Samples.
PART 2: EXPERIMENTS FOR AIR SAMPLES.
4. Determination of Henry s Law Constants.
5. Global Warming: Determining If a Gas Is Infrared Active.
6. Monitoring the Presence of Hydrocarbons in Air around Gasoline Stations.
PART 3: EXPERIMENTS FOR WATER SAMPLES.
7. Determination of an Ion Balance for a Water Sample.
8. Measuring the Concentration of Chlorinated Pesticides in Water Samples.
9. Determination of Chloride, Bromide, and Fluoride in Water Samples.
10. Analysis of Nickel Solutions by Ultraviolet Visible Spectrometry.
PART 4: EXPERIMENTS FOR HAZARDOUS WASTE.
11. Determination of the Composition of Unleaded Gasoline Using Gas Chromatography.
12. Precipitation of Metals from Hazardous Waste.
13. Determination of the Nitroaromatics in Synthetic Wastewater from a Munitions Plant.
14. Determination of a Surrogate Toxic Metal in a Simulated Hazardous Waste Sample.
15. Reduction of Substituted Nitrobenzenes by Anaerobic Humic Acid Solutions.
PART 5: EXPERIMENTS FOR SEDIMENT AND SOIL SAMPLES.
16. Soxhlet Extraction and Analysis of a Soil or Sediment Sample Contaminated with n–Pentadecane.
17. Determination of a Clay Water Distribution Coefficient for Copper.
PART 6: WET EXPERIMENTS.
18. Determination of Dissolved Oxygen in Water Using the Winkler Method.
19. Determination of the Biochemical Oxygen Demand of Sewage Influent.
20. Determination of Inorganic and Organic Solids in Water Samples: Mass Balance Exercise.
21. Determination of Alkalinity of Natural Waters.
22. Determination of Hardness in a Water Sample.
PART 7: FATE AND TRANSPORT CALCULATIONS.
23. pC pH Diagrams: Equilibrium Diagrams for Weak Acid and Base Systems.
24. Fate and Transport of Pollutants in Rivers and Streams.
25. Fate and Transport of Pollutants in Lake Systems.
26. Fate and Transport of Pollutants in Groundwater Systems.
27. Transport of Pollutants in the Atmosphere.
28. Biochemical Oxygen Demand and the Dissolved Oxygen Sag Curve in a Stream: Streeter Phelps Equation.
APPENDIX A: Periodic Table.
"...a good reference for educators involved in the design of an introductory environmental or instrumental chemistry laboratory." (Journal of Chemical Education, March 2005)
"Dunnivant offers some very good experiments in this book...the student CD–ROM was easy to enter and use." (CHOICE, February 2005)
" this volume is an excellent set of environmental/analytical chemistry experiment." (Microchemical Journal, December 17, 2004)
"This textbook lays out standards for lab notebooks that might one day become evidence in a pollution case." (Environmental Science & Technology, December 2004)