50 and More Essential NMR Experiments. A Detailed Guide

  • ID: 2392688
  • Book
  • 316 Pages
  • John Wiley and Sons Ltd
1 of 4
This book is the perfect link for learning how to perform the experiments after only having studied theory. In eight chapters more than 50 essential NMR experiments are described in detail. Special focus is put on the organic set of NMR spectra (1H, 13C–APT, COSY, NOESY, HSQC and HMBC). Different chapters deal with advanced organic

NMR, selective methods, heteronuclear NMR, relaxation and diffusion measurements, organic applications and maintenance. Every experiment has a section providing the reader with the purpose and scope of the specific experiment. Every experiment is concluded with the spectrum as it is obtained under the conditions described. Questions and comments enable the reader to check their understanding. The authors are very

experienced and the whole book is in full color, which enhances the reading experience and makes the spectra and other figures easier to understand.

This book is strongly recommended for all students and researchers who are involved in the structural elucidation of chemical compounds both in practical education and in pursuing research, in particular if they handle an NMR spectrometer.
Note: Product cover images may vary from those shown
2 of 4
PREFACE

THE ORGANIC SET OF NMR SPECTRA

The 1H NMR Experiment

APT–13C NMR

COSY

NOESY

HSQC

HMBC

ADVANCED ORGANIC NMR SPECTROSCOPY

2D J–Resolved 1H NMR Spectroscopy

ROESY

TOCSY

HSQC–TOCSY

HOESY

INADEQUATE

ADEQUATE

J–HMBC

Gated Decoupling

SELECTIVE METHODS

Water suppression by Presaturation

Solvent Suppression by 1D–NOESY

Water Suppression by SOGGY Excitation Sculpting

Solvent Suppression using WET

SELTOCSY

SELNOESY

SELINCOR

SELINQUATE

Band Selective HMBC

HETERONUCLEAR NMR

11B NMR Spectroscopy

15N NMR Spectroscopy

17O NMR Spectroscopy

19F NMR Spectroscopy

29Si NMR Spectroscopy

57Fe NMR Spectroscopy

195Pt NMR Spectroscopy

EXPERIMENTS IN PHYSICAL ORGANIC CHEMISTRY

Measurement of the Spin –

Lattice Relaxation Time T1

Measurement of the Spin –

Spin Relaxation Time T2

Dynamic 1H NMR Spectroscopy

Diffusion Measurement with DOSY

Residual Dipolar Couplings (RDC)

ORGANIC CHEMISTRY APPLICATIONS

ASIS

Chirality Determination

Advanced Mosher Method

Quantitative NMR and Relaxation Reagents

Determination of Association Constants Ka

STD NMR

A Kinetic Experiment

AN EXCURSION TO THE SOLID STATE AND TO STRUCTURAL BIOLOGY

The CP/MAS Experiment

High–Resolution Magic–Angle Spinning

HN–HSQC

HNCA

MAINTENANCE AND CALIBRATION

Calibration of Pulse Duration in the Transmitter Channel

Calibration of the Pulse Duration in the Indirect Channel

Shaped Pulses

Adiabatic pulses

Temperature Calibration in NMR

Calibration of Pulsed Field Gradients

APPENDIX

Answers

Pulse Programs

Elementary Product Operator Formalism Rules

Chemical Shift and Spin–Coupling Data for Strychnine

Picture Credits

INDEX

Note: Product cover images may vary from those shown
3 of 4

Loading
LOADING...

4 of 4
Matthias Findeisen
Stefan Berger
Note: Product cover images may vary from those shown
5 of 4
Note: Product cover images may vary from those shown
Adroll
adroll