Diffusion in Nanoporous Materials. Edition No. 1

Table of Contents

Volume 1

PART I: Introduction

ELEMENTARY PRINCIPLES OF DIFFUSION
Fundamental Definitions
Driving Force for Diffusion
Diffusional Resistances in Nanoporous Media
Experimental Methods

PART II: Theory

DIFFUSION AS A RANDOM WALK
Random Walk Model
Correlation Effects
Boundary Conditions
Macroscopic and Microscopic Diffusivities
Correlating Self-Diffusion and Diffusion with a Simple Jump Model
Anomalous Diffusion

DIFFUSION AND NON-EQUILIBRIUM THERMODYNAMICS
Generalized Forces and Fluxes
Self-Diffusion and Diffusive Transport
Generalized Maxwell -
Stefan Equations
Application of the Maxwell -
Stefan Model
Loading Dependence of Self- and Transport Diffusivities
Diffusion at High Loadings and in Liquid-Filled Pores

DIFFUSION MECHANISMS
Diffusion Regimes
Diffusion in Macro- and Mesopores
Activated Diffusion 99
Diffusion in More Open Micropore Systems

SINGLE-FILE DIFFUSION
Infinitely Extended Single-File Systems
Finite Single-File Systems
Experimental Evidence

SORPTION KINETICS
Resistances to Mass and Heat Transfer
Mathematical Modeling of Sorption Kinetics
Sorption Kinetics for Binary Mixtures

PART III: Molecular Modeling

CONSTRUCTING MOLECULAR MODELS AND SAMPLING EQUILIBRIUM PROBABILITY DISTRIBUTIONS
Models and Force Fields for Zeolite -
Sorbate Systems
Monte Carlo Simulation Methods
Free Energy Methods for Sorption Equilibria
Coarse-Graining and Potentials of Mean Force

MOLECULAR DYNAMICS SIMULATIONS
Statistical Mechanics of Diffusion
Equilibrium Molecular Dynamics Simulations
Non-Equilibrium Molecular Dynamics Simulations

INFREQUENT EVENT TECHNIQUES FOR SIMULATING DIFFUSION IN MICROPOROUS SOLIDS
Statistical Mechanics of Infrequent Events
Tracking Temporal Evolution in a Network of States
Example Applications of Infrequent Event Analysis and Kinetic Monte Carlo for the Prediction of Diffusivities in Zeolites

PART IV: Measurement Methods
MEASUREMENT OF ELEMENTARY DIFFUSION PROCESSES
NMR Spectroscopy
Diffusion Measurements by Neutron Scattering
Diffusion Measurements by Light Scattering

DIFFUSION MEASUREMENT BY MONITORING MOLECULAR DISPLACEMENT
Pulsed Field Gradient (PFG) NMR: Principle of Measurement
The Complete Evidence of PFG NMR
Experimental Conditions, Limitations, and Options for PFG NMR Diffusion Measurement
Different Regimes of PFG NMR Diffusion Measurement
Experimental Tests of Consistency
Single-Molecule Observation

IMAGING OF TRANSIENT CONCENTRATION PROFILES
Different Options of Observation
Monitoring Intracrystalline Concentration Profiles by IR and Interference Microscopy
New Options for Experimental Studies

DIRECT MACROSCOPIC MEASUREMENT OF SORPTION AND TRACER EXCHANGE RATES
Gravimetric Methods
Piezometric Method 433
Macro FTIR Sorption Rate Measurements
Rapid Recirculation Systems
Differential Adsorption Bed 441
Analysis of Transient Uptake Rate Data
Tracer Exchange Measurements
Frequency Response Measurements

CHROMATOGRAPHIC AND PERMEATION METHODS OF MEASURING INTRAPARTICLE DIFFUSION
Chromatographic Method
Deviations from the Simple Theory
Experimental Systems for Chromatographic Measurements
Analysis of Experimental Data
Variants of the Chromatographic Method
Chromatography with Two Adsorbable Components
Zero-Length Column (ZLC) Method
TAP System
Membrane Permeation Measurements Volume 2

PART V: Diffusion in Selected Systems

AMORPHOUS MATERIALS AND EXTRACRYSTALLINE (MESO/MACRO) PORES
Diffusion in Amorphous Microporous Materials
Effective Diffusivity
Diffusion in Ordered Mesopores
Surface Diffusion
Diffusion in Liquid-Filled Pores
Diffusion in Hierarchical Pore Systems
Diffusion in Beds of Particles and Composite Particles
More Complex Behavior: Presence of a Condensed Phase

EIGHT-RING ZEOLITES
Eight-Ring Zeolite Structures
Diffusion in Cation-Free Eight-Ring Structures
Diffusion in 4A Zeolite
Diffusion in 5A Zeolite
General Patterns of Behavior in Type A Zeolites
Window Blocking
Variation of Diffusivity with Carbon Number
Diffusion of Water Vapor in LTA Zeolites
Deactivation, Regeneration, and Hydrothermal Effects
Anisotropic Diffusion in CHA
Concluding Remarks

17 LARGE PORE (12-RING) ZEOLITES
Structure of X and Y Zeolites
Diffusion of Saturated Hydrocarbons
Diffusion of Unsaturated and Aromatic Hydrocarbons In NaX
Other Systems
PFG NMR Diffusion Measurements with Different Probe Nuclei
Self-diffusion in Multicomponent Systems

MEDIUM-PORE (TEN-RING) ZEOLITES
MFI Crystal Structure
Diffusion of Saturated Hydrocarbons
Diffusion of Aromatic Hydrocarbons
Adsorption from the Liquid Phase
Microscale Studies of other Guest Molecules
Surface Resistance and Internal Barriers
Diffusion Anisotropy
Diffusion in a Mixed Adsorbed Phase
Guest Diffusion in Ferrierite

METAL ORGANIC FRAMEWORKS (MOFS)
A New Class of Porous Solids
MOF-5 and HKUST-1: Diffusion in Pore Spaces with the Architecture of Zeolite LTA
Zeolitic Imidazolate Framework 8 (ZIF-8)
Pore Segments in Single-File Arrangement: Zn(tbip)
Breathing Effects: Diffusion in MIL-53
Surface Resistance
Concluding Remarks

PART VI: Selected Applications

ZEOLITE MEMBRANES
Zeolite Membrane Synthesis
Single-Component Permeation
Separation of Gas Mixtures
Modeling Permeation of Binary Mixtures
Membrane Characterization
Membrane Separation Processes

DIFFUSIONAL EFFECTS IN ZEOLITE CATALYSTS
Diffusion and Reaction in a Catalyst Particle
Determination of Intracrystalline Diffusivity from Measurements of Reaction Rate
Direct Measurement of Concentration Profiles during a Diffusion-Controlled Catalytic Reaction
Diffusional Restrictions in Zeolite Catalytic Processes
Coking of Zeolite Catalysts

Authors

Douglas M. Ruthven University of Maine, Orono, USA. Jörg Kärger University of Leipzig, Leipzig, Germany. Doros N. Theodorou National Technical University of Athens, Athens, Greece.