Pincer Compounds

  • ID: 4398643
  • Book
  • 475 Pages
  • Elsevier Science and Technology
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Pincer Compounds: Chemistry and Applications offers valuable state-of-the-art coverage highlighting highly active areas of research-from mechanistic work to synthesis and characterization. The book focuses on small molecule activation chemistry (particularly H2 and hydrogenation), earth abundant metals (such as Fe), actinides, carbene-pincers, chiral catalysis and alternative solvent usage. The book covers the current state of the field, featuring chapters from renowned contributors, covering four continents and ranging from still-active pioneers to new names emerging as creative strong contributors to this fascinating and promising area.

Over a decade since the publication of Morales-Morales and Jensen's The Chemistry of Pincer Compounds (Elsevier, 2007), research in this unique area has flourished, finding a plethora of applications in almost every single branch of chemistry-from their traditional application as very robust and active catalysts all the way to potential biological and pharmaceutical applications.

  • Describes the chemistry and applications of this important class of organometallic and coordination compounds
  • Includes contributions from global leaders in the field, featuring pioneers in the area as well as emerging experts conducting exciting research on pincer complexes
  • Highlights areas of promising and active research, including small molecule activation, earth abundant metals and actinide chemistry
  • Focuses on small molecule activation chemistry (particularly H2 and hydrogenation), earth abundant metals (such as Fe), actinides, carbene-pincers, chiral catalysis and alternative solvent usage
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Note: several contributors are still considering their chapter titles: 1. Chiral Pincer Complexes for Asymmetric Reactions 2. TBD 3. The chemistry of NCN (monoanionic) and NNN (charged and neutral) systems of group 13 to 15 metals especially in unusually low oxidation states 4. Reduction of CO2 Mediated or Catalyzed by Pincer Complexes 5. Mechanistic insights of hydrogenation and dehydrogenation reactions catalyzed by ruthenium and iron pincer complexes 6. Hydrogenation and Dehydrogenation Reactions Catalyzed by Fe Pincer Compounds 7. Actinide Pincer Complexes 8. NHC-based pincer ligands 9. Transition-Metal Pincer Complexes with Chiral Imidazoline Donors and Asymmetric Catalysis 10. Chiral NCN Pincer type catalysts having oxazolines and imidazolines 11. Pincer ligands with a central sp3-hybridized carbon atom 12. CCC-NHC pincer complexes 13. Metal pincer catalysts in aqueous media 14. Amide- and Thioamide-Based Pincers as Anion and Transition Metal Hosts/Ligands 15. Pincer Complexes of Iron in Catalysis" and "Alkane Dehydrogenation Utilizing Pincer Iridium Complexes 16. Activation of sigma-bonds promoted by POP pincer complexes of platinum group metals 17. 'Pincer'-carbenoid complexes with late-transition metals 18. Pincer iridium and ruthenium complexes for alkane dehydrogenation 19. Silicon-based pincers 20.Transition metal complexes with thiolate-based pincer ligands 21. Recent Developments in PSiP Transition Metal Pincer Chemistry 22. TBD 23. NHC Pincer Silver Complexes and Their Transmetallation Chemistry

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Morales-Morales, David

David Morales Morales carried out his B.Sc. (1992) and M.Sc. (1995) studies at the School of Chemistry of the Universidad Nacional Autónoma de México (UNAM). In 1995 he was awarded a scholarship by the Mexican Government to carry out Doctoral studies at the University of Essex (UK) under the supervision of Prof. Jonathan R. Dilworth. In 1997, he moved to the "Inorganic Chemistry Laboratory” at the Oxford University (UK), getting his Doctorate in 1998. In the same year Prof. Morales-Morales was offered a posdoctoral position by Prof. Craig. M. Jensen in the Department of Chemistry of the University of Hawaii at Manoa, USA, where he carried out research relevant to the development of a new generation of PCP pincer complex and their use in C-H activation and C-C bond formation.

A beneficiary of the National Program for Repatriation of the National Science and Technology Council (CONACyT-México), Prof. Morales-Morales has worked since May 2001 as a researcher at the Instituto de Química-UNAM. His research interests include 1) the Chemistry of Pincer Compounds; 2) the synthesis of phosphorus and sulphur-based compounds and its use as ligands with transition metals; 3) metal-mediated organic synthesis; and 4) mechanistic studies.

Prof. Morales-Morales has published more than 60 papers and a chapter in the book "Modern Coordination Chemistry”, edited by the Royal Society of Chemistry (2002). More recently he has served as editor of the book "The Chemistry of Pincer Compounds” (Elsevier) and he has co-authored a textbook on Organometallic Chemistry, published in Spanish by UNAM. He belongs to chemistry societies in Mexico and the United States. Prof. Morales-Morales has been a visiting professor at the Instituto de Materiales de Aragón-CSIC (Zaragoza, Spain), The Anorganisch-Chemisches Institut der WWU Münster in Germany, and the Metal Mediated Synthesis - Debye Institute at the University of Utretch (Netherlands).

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