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The Global Market for CVD Graphene

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    Report

  • 220 Pages
  • July 2018
  • Region: Global
  • Future Markets, Inc
  • ID: 4591130

Chemical Vapor Deposition (CVD) is the favoured approach for the production of large area graphene films for application as transparent conductive layers in flexible electronics, touchscreens, sensors, and energy. This approach is industrially-scalable and produces films that have higher quality, homogeneity and are cheaper than those produced by chemical exfoliation.

The high-value applications for graphene generally require graphene films (solar cells, electronics, transparent electrodes, ultracapacitors, etc.). However, preparation of large-area, defect-free, continuous graphene film remains a challenge. Large consumer electronics companies are heavily involved in product development in this segment along with a number of smaller companies developing CVD Graphene films that be mass-produced and transferred to nearly any substrate. Low cost production and etch-free transfer of graphene films could potentially disrupt multi-billion dollar markets including sensors, energy storage, and flexible electronics.

Report contents include:

  • Stage of commercialization for CVD graphene applications, from basic research to market entry.
  • Market drivers, trends and challenges, by end user markets.
  • Market outlook for 2018.
  • In-depth market assessment of opportunities for CVD graphene in electronic, optoelectronics, biosensors and energy storage .
  • Production capacities by company (m2).
  • In-depth company profiles, including products, capacities, and commercial activities.
  • Detailed forecasts for key growth areas, opportunities and user demand.
  • Assessment of applications for other 2D materials competitive with and complementary to CVD graphene.
  • 42 company profiles.


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Table of Contents

1 RESEARCH METHODOLOGY
1.1 Market opportunity analysis
1.2 Market challenges rating system
2 EXECUTIVE SUMMARY
2.1 Two-dimensional (2D) materials
2.2 CVD Graphene
2.2.1 The market in 2018
2.2.2 Products
2.2.3 Production
3 OVERVIEW OF GRAPHENE
3.1 History
3.2 Forms of graphene
3.3 Properties
4 CVD GRAPHENE SYNTHESIS
4.1 CVD Graphene
4.2 Production methods
4.3 Graphene quality
4.4 Synthesis and production of CVD graphene
4.5 Pros and cons of CVD production
5 END USER MARKET SEGMENT ANALYSIS
5.1 Commercial production capacities
5.1.1 CVD graphene film production by country/year, 2010-2018/ 000s m2
5.2 Graphene pricing
5.2.1 Pristine Graphene Flakes pricing
5.2.2 Few-Layer Graphene pricing
5.2.3 Graphene Nanoplatelets pricing
5.2.4 Reduced Graphene Oxide pricing
5.2.5 Graphene Quantum Dots pricing
5.2.6 Graphene Oxide Nanosheets pricing
5.2.7 Multilayer Graphene (MLG) pricing
5.2.8 Mass production of lower grade graphene materials
5.2.9 High grade graphene difficult to mass produce
5.2.10 Bulk supply
5.2.11 Commoditisation
6 MARKETS FOR CVD GRAPHENE
6.1 ELECTRONICS
6.1.1 FLEXIBLE ELECTRONICS, WEARABLES, CONDUCTIVE FILMS AND DISPLAYS
6.1.1.1 MARKET DRIVERS AND TRENDS
6.1.1.2 PROPERTIES AND APPLICATIONS
6.1.1.3 GLOBAL MARKET SIZE AND OPPORTUNITY
6.1.1.4 MARKET CHALLENGES
6.2 TRANSISTORS AND INTEGRATED CIRCUITS
6.2.1 MARKET DRIVERS AND TRENDS
6.2.2 PROPERTIES AND APPLICATIONS
6.2.2.1 Integrated circuits
6.2.2.2 Transistors
6.2.2.3 Graphene Radio Frequency (RF) circuits
6.2.2.4 Graphene spintronics
6.2.3 GLOBAL MARKET SIZE AND OPPORTUNITY
6.2.4 MARKET CHALLENGES
6.3 MEMORY DEVICES
6.3.1 MARKET DRIVERS AND TRENDS
6.3.2 PROPERTIES AND APPLICATIONS
6.3.3 GLOBAL MARKET SIZE AND OPPORTUNITY
6.3.4 MARKET CHALLENGES
6.4 PHOTONICS
6.4.1 MARKET DRIVERS AND TRENDS
6.4.2 PROPERTIES AND APPLICATIONS
6.4.2.1 Si photonics versus graphene
6.4.2.2 Optical modulators
6.4.2.3 Photodetectors
6.4.2.4 Saturable absorbers
6.4.2.5 Plasmonics
6.4.2.6 Fiber lasers
6.4.3 GLOBAL MARKET SIZE AND OPPORTUNITY
6.4.4 MARKET CHALLENGES
7 SUPERCAPACITORS
7.1 MARKET DRIVERS AND TRENDS
7.2 PROPERTIES AND APPLICATIONS
7.2.1 Flexible and stretchable supercapacitors
7.3 GLOBAL MARKET SIZE AND OPPORTUNITY
7.4 MARKET CHALLENGES
8 PHOTOVOLTAICS
8.1 MARKET DRIVERS AND TRENDS
8.2 PROPERTIES AND APPLICATIONS
8.2.1. ITO replacement
8.2.2 Graphene-silicon (Gr-Si) Schottky junction solar cells
8.2.3 Halide perovskites/graphene hybrids
8.2.4 Solar energy harvesting textiles
8.3 GLOBAL MARKET SIZE AND OPPORTUNITY
8.4 MARKET CHALLENGES
9 FLEXIBLE LED LIGHTING
9.1 MARKET DRIVERS AND TRENDS
9.2 PROPERTIES AND APPLICATIONS
9.2.1 Flexible OLED lighting
9.3 GLOBAL MARKET SIZE AND OPPORTUNITY
9.4 MARKET CHALLENGES
10 BIOSENSORS
10.1 MARKET DRIVERS AND TRENDS
10.2 PROPERTIES AND APPLICATIONS
10.3 GLOBAL MARKET SIZE AND OPPORTUNITY
10.4 MARKET CHALLENGES
11 CVD GRAPHENE PRODUCER AND PRODUCT DEVELOPERS PROFILES12 APPENDIX 1: OTHER 2-D MATERIALS13 REFERENCES
LIST OF TABLES
Table 1: CVD graphene target markets-Applications and potential addressable market size
Table 2: Main CVD graphene producers by country and annual production capacities, m2
Table 3: Properties of graphene
Table 4: CVD graphene-Markets, applications and current global market
Table 5: Main production methods for graphene
Table 6: Large area graphene films-Markets, applications and current global market
Table 7: CVD graphene film capacity by country/year, 2010-2018/ 000s m2
Table 8: Types of graphene and prices
Table 9: Pristine graphene flakes pricing by producer
Table 10: Few-layer graphene pricing by producer
Table 11: Graphene nanoplatelets pricing by producer
Table 12: Reduced graphene oxide pricing, by producer
Table 13: Graphene quantum dots pricing by producer
Table 14: Graphene oxide nanosheets pricing by producer
Table 15: Multi-layer graphene pricing by producer
Table 16: Market drivers for use of CVD graphene in flexible electronics and conductive films
Table 17: Applications and benefits of CVD graphene in flexible electronics and conductive films
Table 18: Comparison of ITO replacements
Table 19: Wearable electronics devices and stage of development
Table 20: Graphene properties relevant to application in sensors
Table 21: Market size for CVD graphene in flexible electronics and conductive films
Table 22: Market opportunity assessment for CVD graphene in flexible electronics, wearables, conductive films and displays
Table 23: Global market for wearable electronics, 2015-2027, by application, billions $
Table 24: Market challenges rating for graphene in the flexible electronics, wearables, conductive films and displays market
Table 25: Market drivers for use of CVD graphene in transistors, integrated circuits and other components
Table 26: Comparative properties of silicon and graphene transistors
Table 27: Applications and benefits of CVD graphene in transistors, integrated circuits and other components
Table 28: Market size for CVD graphene in transistors, integrated circuits and other components
Table 29: Market opportunity assessment for CVD graphene in transistors, integrated circuits and other components
Table 30: Market challenges rating for graphene in the transistors and integrated circuits market
Table 31: Market drivers for use of CVD graphene in memory devices
Table 32: Market size for CVD graphene in memory devices
Table 33: Applications and commercialization challenges for graphene in the memory devices market
Table 34: Market drivers for use of CVD graphene in photonics
Table 35: Graphene properties relevant to application in optical modulators
Table 36: Applications and benefits of graphene in photonics
Table 37: Market size for CVD graphene in photonics
Table 38: Market challenges rating for graphene in the photonics market
Table 39: Market drivers for use of CVD graphene in supercapacitors
Table 40: Comparative properties of graphene supercapacitors and lithium-ion batteries
Table 41: Applications and benefits of CVD graphene in supercapacitors
Table 42: Market size for CVD graphene in supercapacitors
Table 43: Market opportunity assessment for CVD graphene in supercapacitors
Table 44: Market challenges rating for graphene in the supercapacitors market
Table 45: Market drivers for use of CVD graphene in photovoltaics
Table 46: Market size for CVD graphene in photovoltaics
Table 47: Market size for CVD graphene in photovoltaics
Table 48: Potential addressable market for photovoltaics
Table 49: Market challenges rating for graphene in the solar market
Table 50: Market drivers for use of CVD graphene in LED lighting and UVC
Table 51: Applications of CVD graphene in lighting
Table 52: Market size for CVD graphene in LED lighting
Table 53: Investment opportunity assessment for CVD graphene in the lighting market
Table 54: Market impediments for graphene in lighting
Table 55: Market drivers for use of CVD graphene in sensors
Table 56: Applications and benefits of graphene in biosensors
Table 57: Graphene properties relevant to application in sensors
Table 58: Comparison of ELISA (enzyme-linked immunosorbent assay) and graphene biosensor
Table 59: Market size for CVD graphene in biosensors
Table 60: Market opportunity assessment for CVD graphene in the biosensors market
Table 61: Market challenges rating for graphene in the sensors market
Table 62: 2D materials types
Table 63: Electronic and mechanical properties of monolayer phosphorene, graphene and MoS2
Table 64: Market opportunity assessment for phosphorene applications
Table 65: Market opportunity assessment for graphitic carbon nitride applications
Table 66: Market opportunity assessment for germanene applications
Table 67: Market opportunity assessment for graphdiyne applications
Table 68: Market opportunity assessment for graphane applications
Table 69: Market opportunity assessment for hexagonal boron nitride applications
Table 70: Market opportunity assessment for molybdenum disulfide applications
Table 71: Market opportunity assessment for Rhenium disulfide (ReS2) and diselenide (ReSe2) applications
Table 72: Market opportunity assessment for silicene applications
Table 73: Market opportunity assessment for stanine/tinene applications
Table 74: Market opportunity assessment for tungsten diselenide applications
Table 75: Comparative analysis of graphene and other 2-D nanomaterials
LIST OF FIGURES
Figure 1: Global consumption of CVD graphene 2017, by region
Figure 2: Graphene layer structure schematic
Figure 3: Graphite and graphene
Figure 4: Graphene and its descendants: top right: graphene; top left: graphite = stacked graphene; bottom right: nanotube=rolled graphene; bottom left: fullerene=wrapped graphene.
Figure 5: Fabrication methods of graphene
Figure 6: Schematic illustration of the main graphene production techniques
Figure 7: Graphene synthesis-CVD technique
Figure 8: CVD Graphene on Cu Foil
Figure 9: Moxi flexible film developed for smartphone application
Figure 10: Flexible graphene touch screen
Figure 11: Galapad Settler smartphone
Figure 12: Flexible organic light emitting diode (OLED) using graphene electrode
Figure 13: Graphene electrochromic devices. Top left: Exploded-view illustration of the graphene electrochromic device. The device is formed by attaching two graphene-coated PVC substrates face-to-face and filling the gap with a liquid ionic electrolyte
Figure 14: Flexible mobile phones with graphene transparent conductive film
Figure 15: Foldable graphene E-paper
Figure 16: Wearable gas sensor
Figure 17: Potential addressable market for CVD graphene in the flexible electronics, wearables, conductive films and displays market
Figure 18: Global market for wearable electronics, 2015-2027, by application, billions $
Figure 19: Global transparent conductive electrodes market forecast by materials type, 2012-2027, millions $
Figure 20: Schematic of the wet roll-to-roll graphene transfer from copper foils to polymeric substrates
Figure 21: The transmittance of glass/ITO, glass/ITO/four organic layers, and glass/ITO/four organic layers/4-layer graphene
Figure 22: Graphene IC in wafer tester
Figure 23: A monolayer WS2-based flexible transistor array
Figure 24: Schematic cross-section of a graphene based transistor (GBT, left) and a graphene field-effect transistor (GFET, right)
Figure 25: Potential addressable market for CVD graphene in transistors and integrated circuits
Figure 26: Potential addressable market for CVD graphene in the transistors and integrated circuits market
Figure 27: Graphene oxide-based RRAm device on a flexible substrate
Figure 28: Layered structure of tantalum oxide, multilayer graphene and platinum used for resistive random access memory (RRAM)
Figure 29: A schematic diagram for the mechanism of the resistive switching in metal/GO/Pt
Figure 30: Carbon nanotubes NRAM chip
Figure 31: Stretchable SWCNT memory and logic devices for wearable electronics
Figure 32: Potential addressable market for CVD graphene in the memory devices market
Figure 33: Hybrid graphene phototransistors
Figure 34: Wearable health monitor incorporating graphene photodetectors
Figure 35: Flexible PEN coated with graphene and a QD thin film (20nm) is highly visibly transparent and photosensitive
Figure 36: Potential addressable market for CVD graphene in photonics
Figure 37: Skeleton Technologies ultracapacitor
Figure 38: Stretchable graphene supercapacitor
Figure 39: Potential addressable market for CVD graphene in supercapacitors
Figure 40: Solar cell with nanowires and graphene electrode
Figure 41: Schematic illustration of the fabrication concept for textile-based dye-sensitized solar cells (DSSCs) made by sewing textile electrodes onto cloth or paper
Figure 42: Potential addressable market for CVD graphene in photovoltaics
Figure 43: LG OLED flexible lighting panel
Figure 44: Flexible OLED incorporated into automotive headlight
Figure 45: Potential addressable market for CVD graphene in lighting
Figure 46: First generation point of care diagnostics
Figure 47: Graphene Field Effect Transistor Schematic
Figure 48: Potential addressable market for CVD graphene in the biosensors market
Figure 49: Schematic of 2-D materials
Figure 50: Black phosphorus structure
Figure 51: Black Phosphorus crystal
Figure 52: Bottom gated flexible few-layer phosphorene transistors with the hydrophobic dielectric encapsulation
Figure 53: Graphitic carbon nitride
Figure 54: Structural difference between graphene and C2N-h2D crystal: (a) graphene; (b) C2N-h2D crystal. Credit: Ulsan National Institute of Science and Technology
Figure 55: Schematic of germanene
Figure 56: Graphdiyne structure
Figure 57: Schematic of Graphane crystal
Figure 58: Structure of hexagonal boron nitride
Figure 59: BN nanosheet textiles application
Figure 60: Structure of 2D molybdenum disulfide
Figure 61: SEM image of MoS2
Figure 62: Atomic force microscopy image of a representative MoS2 thin-film transistor
Figure 63: Schematic of the molybdenum disulfide (MoS2) thin-film sensor with the deposited molecules that create additional charge
Figure 64: Schematic of a monolayer of rhenium disulfide
Figure 65: Silicene structure
Figure 66: Monolayer silicene on a silver (111) substrate
Figure 67: Silicene transistor
Figure 68: Crystal structure for stanene
Figure 69: Atomic structure model for the 2D stanene on Bi2Te3(111)
Figure 70: Schematic of tungsten diselenide
Figure 71: Schematic of Indium Selenide (InSe)

Methodology

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